Biosynthesis of Chloromethane in Phellinus pomaceus
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چکیده
منابع مشابه
Chloromethane, a Novel Methyl Donor for Biosynthesis of Esters and Anisoles in Phellinus pomaceus.
Chloromethane (CH(3)Cl), a gaseous natural product released as a secondary metabolite by many woodrotting fungi of the family Hymenochaetaceae, has been shown to act as a methyl donor for biosynthesis of methyl esters of benzoic and furoic acid in the primary metabolism of Phellinus pomaceus. The broad-specificity methylating system could esterify a wide range of aromatic and aliphatic acids. I...
متن کاملThe methylation of benzoic and n-butyric acids by chloromethane in Phellinus pomaceus
The kinetics of carboxylic acid methylation by chloromethane (CH3Cl) in myceliaaf the fungus Phellinus pomaceus were examined. Substantial incorporation of C2H3into ester was observed within 5 min of addition of C2H3Cl to washed mycelia in the presence of the non-physiological acceptor butyric acid, rendering it unlikely that CH3Cl was converted to a diffusible intermediate before acting as met...
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Kinetic isotope effects in the gas phase reactions of OH and Cl with CH3Cl, CD3Cl, and CH3Cl A. A. Gola, B. D’Anna, K. L. Feilberg, S. R. Sellevåg, L. Bache-Andreassen, and C. J. Nielsen Department of Chemistry, University of Oslo, P.O.Box 1033 Blindern, N-0315 Oslo, Norway Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark permanent address: De...
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New insight into the atmospheric chloromethane budget gained using stable carbon isotope ratios F. Keppler, D. B. Harper, T. Röckmann, R. M. Moore, and J. T. G. Hamilton School of Agriculture and Food Science, Queen’s University Belfast, Newforge Lane, Belfast BT9 5PX, UK Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, 69117 Heidelberg, Germany Department of Oceanography, Dalhousie Unive...
متن کاملTransfer of a Catabolic Pathway for Chloromethane in Methylobacterium Strains Highlights Different Limitations for Growth with Chloromethane or with Dichloromethane
Chloromethane (CM) is an ozone-depleting gas, produced predominantly from natural sources, that provides an important carbon source for microbes capable of consuming it. CM catabolism has been difficult to study owing to the challenging genetics of its native microbial hosts. Since the pathways for CM catabolism show evidence of horizontal gene transfer, we reproduced this transfer process in t...
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ژورنال
عنوان ژورنال: Microbiology
سال: 1988
ISSN: 1350-0872,1465-2080
DOI: 10.1099/00221287-134-10-2831